Episode 49 - "Asura's Awakening: The Arrival of the World's End?"
Asura, being injured from the battle with Shinigami, put up a barrier and the only ones to make is inside are Maka, Black Star, and Kid with there weapons. When they start to fight Asura they don't appear to be injuring, but Kid thinks they are because the barrier is weakening. They then start a chain resonance with Soul playing the piano. When Maka is about to preform Demon Hunter, Soul's soul is devoured by the black blood. With Soul, the only one who can help them do a chain resonance, down for the count Maka goes to bring Soul back, with Black Star and Kid protecting her.
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